Diethyl malonate, also known as DEM, is the diethyl ester of malonic acid. It occurs naturally in grapes and strawberries as a colourless liquid with...
9 KB (765 words) - 20:59, 8 February 2024
Malonic acid (redirect from Malonate)
well as its esters and salts, are known as malonates. For example, diethyl malonate is malonic acid's diethyl ester. The name originates from the Greek...
20 KB (1,985 words) - 02:27, 6 September 2024
Diethyl diethylmalonate or diethyl 2,2-diethylmalonate is a derivative of diethyl malonate. It can be used in the synthesis of barbital. As being a diethyl...
2 KB (75 words) - 18:59, 1 May 2024
Malonic ester synthesis (redirect from Malonate ester synthesis)
The malonic ester synthesis is a chemical reaction where diethyl malonate or another ester of malonic acid is alkylated at the carbon alpha (directly adjacent)...
4 KB (315 words) - 22:53, 28 March 2024
producer of dimethyl malonate by volume and uses a chloroacetic acid/sodium cyanide process developed in the 1940s. Diethyl malonate Merck Index, 11th Edition...
3 KB (252 words) - 16:31, 8 June 2024
relatively weaker electrophiles than alkyl halides and thus poorly alkylate diethyl malonate. Methods using Caesium carbonate and copper(I) iodide have been developed...
3 KB (180 words) - 01:42, 19 September 2022
are the reaction between diethyl malonate (Michael donor) and diethyl fumarate (Michael acceptor), that of diethyl malonate and mesityl oxide (forming...
27 KB (2,825 words) - 08:27, 20 March 2024
co-workers obtained by the nitrosation of diethyl malonate its isonitrosoester, which was oxidized to diethyl oxomalonate with dinitrogen tetroxide N2O4...
13 KB (1,343 words) - 15:06, 11 October 2021
acetoacetate is often used in the acetoacetic ester synthesis, comparable to diethyl malonate in the malonic ester synthesis or the Knoevenagel condensation. After...
8 KB (686 words) - 23:38, 14 August 2024
Barbital (redirect from Diethyl barbituric acid)
synthesized in a condensation reaction from urea and diethyl-2,2-diethylmalonate, a diethyl malonate derivative: Barbital was marketed in 1904 by the Bayer...
13 KB (1,216 words) - 04:47, 29 September 2024