P-Chiral phosphines are organophosphorus compounds of the formula PRR′R″, where R, R′, R″ = H, alkyl, aryl, etc. They are a subset of chiral phosphines...

are not in the same plane, such as phosphorus in P-chiral phosphines (PRR′R″) and sulfur in S-chiral sulfoxides (OSRR′), because a lone-pair of electrons...

the olefin, fixing the stereochemistry. Note that only part of the chiral phosphine ligand is shown for the sake of clarity. Quadrant model for asymmetric...

a Lewis acid cocatalyst was required to accelerate the reaction. P-Chiral phosphines have been investigated. Simple diamines can also be employed as MBH...

acrylonitrile: PH3 + 3 CH2=CHZ → P(CH2CH2Z)3 (Z = NO2, CN, C(O)NH2) Tertiary phosphines of the type PRR′R″ are "P-chiral" and optically stable. From the...

optically stable (enantiomers racemize rapidly at room temperature), but P-chiral phosphines are. Appropriately substituted sulfonium salts, sulfoxides, arsines...

phosphorus. With four different substituents (O, OH, H, R) they are chiral. The primary phosphine oxides subject to tautomerization, which leads to racemization...

the achiral triphenylphosphine ligands in Wilkinson's catalyst with chiral phosphine ligands. This experimental catalyst was employed in an asymmetric hydrogenation...

Homochirality is a uniformity of chirality, or handedness. Objects are chiral when they cannot be superposed on their mirror images. For example, the left...

Ohyun. "Phosphine-Catalyzed Annulations and Their Applications". {{cite journal}}: Cite journal requires |journal= (help) "Kwon Phosphines: P-Chiral Monodentate...