The Cope reaction or Cope elimination, developed by Arthur C. Cope, is the elimination reaction of an N-oxide to an alkene and a hydroxylamine. Typically...
6 KB (552 words) - 19:45, 3 April 2024
The Cope rearrangement is an extensively studied organic reaction involving the [3,3]-sigmatropic rearrangement of 1,5-dienes. It was developed by Arthur...
9 KB (1,087 words) - 21:52, 19 February 2024
Rearrangements, especially those that can participate in cascade reactions, such as the aza-Cope rearrangements, are of high practical as well as conceptual...
50 KB (5,704 words) - 20:45, 22 July 2024
oxy-Cope rearrangement is a chemical reaction. It involves reorganization of the skeleton of certain unsaturated alcohols. It is a variation of the Cope rearrangement...
15 KB (1,780 words) - 18:43, 3 December 2023
form intermediates in analogous reactions. The most well-known of the sigmatropic rearrangements are the [3,3] Cope rearrangement, Claisen rearrangement...
18 KB (2,106 words) - 11:04, 20 May 2024
Alkene (section Reaction overview)
elimination) or oxidized to an amine oxide (the Cope reaction) to render a smooth elimination possible. The Cope reaction is a syn-elimination that occurs at or...
48 KB (5,122 words) - 23:58, 18 July 2024
sigmatropic reaction such as the Cope rearrangement. Cyclic rearrangements include cycloadditions and, more generally, pericyclic reactions, wherein two...
66 KB (8,031 words) - 09:58, 12 July 2024
Amine oxide (redirect from Polonovski reaction)
reactions. Pyrolytic elimination. Amine oxides, when heated to 150–200 °C undergo a Cope reaction to form a hydroxylamine and an alkene. The reaction...
12 KB (1,327 words) - 17:22, 31 July 2024
Ei mechanism (redirect from Ei reaction)
rate of elimination and the final yield of the olefin. The Cope elimination (Cope reaction) is the elimination of a tertiary amine oxide to yield an alkene...
17 KB (2,002 words) - 06:27, 8 February 2023