In organic chemistry, a cycloaddition is a chemical reaction in which "two or more unsaturated molecules (or parts of the same molecule) combine with...
11 KB (1,261 words) - 17:18, 22 January 2024
cycloaddition is a chemical reaction between a 1,3-dipole and a dipolarophile to form a five-membered ring. The earliest 1,3-dipolar cycloadditions were...
65 KB (6,396 words) - 21:04, 1 August 2024
The azide-alkyne Huisgen cycloaddition is a 1,3-dipolar cycloaddition between an azide and a terminal or internal alkyne to give a 1,2,3-triazole. Rolf...
21 KB (2,639 words) - 20:31, 22 July 2024
better than others:[clarification needed] [3+2] cycloadditions, such as the Huisgen 1,3-dipolar cycloaddition, in particular the Cu(I)-catalyzed stepwise...
48 KB (5,450 words) - 19:30, 21 October 2024
Trimethylenemethane cycloaddition is the formal (3+2) annulation of trimethylenemethane (TMM) derivatives to two-atom pi systems. Although TMM itself...
12 KB (1,457 words) - 04:24, 2 September 2024
fulfill the requirements of bioorthogonality, including the 1,3-dipolar cycloaddition between azides and cyclooctynes (also termed copper-free click chemistry)...
44 KB (5,098 words) - 05:29, 19 February 2024
Ketene cycloadditions are the reactions of the pi system of ketenes with unsaturated compounds to provide four-membered or larger rings. [2+2], [3+2],...
9 KB (1,180 words) - 00:32, 24 August 2024
In organic chemistry, enone–alkene cycloadditions are a version of the [2+2] cycloaddition. This reaction involves an enone and alkene as substrates....
9 KB (1,024 words) - 06:19, 29 April 2024
of an iminium ion next to a carbanion. They are used in 1,3-dipolar cycloaddition reactions to form five-membered heterocycles, including pyrrolidines...
18 KB (1,988 words) - 01:46, 19 April 2024
Woodward–Hoffmann rules (redirect from 2+2 Cycloaddition)
formidable (up to ca. 5 eV or 480 kJ/mol in the case of a forbidden [2+2] cycloaddition), the prohibition is not absolute, and symmetry-forbidden reactions...
93 KB (11,923 words) - 14:39, 12 August 2024