High-valent iron commonly denotes compounds and intermediates in which iron is found in a formal oxidation state > 3 that show a number of bonds > 6 with...
11 KB (1,437 words) - 12:08, 25 June 2024
Lawrence Que Jr. (section High-valent iron-oxos)
studying the behaviors of high-valent iron-oxo species in relation to their ability of hydroxylation. Previous high-valent iron-oxo species have been noted...
15 KB (1,394 words) - 00:37, 3 October 2023
hemoglobin, cytochrome (see high-valent iron), and catalase. The average adult human contains about 0.005% body weight of iron, or about four grams, of which...
150 KB (17,056 words) - 12:22, 24 August 2024
organometallic chemistry. Many coordination compounds of iron are known, although few exhibit high-valent iron. A typical six-coordinate anion is hexachloroferrate(III)...
27 KB (2,957 words) - 03:23, 7 August 2024
release N2, generating a metal complex in unusual oxidation states (see high-valent iron). Azides have an ambivalent redox behavior: they are both oxidizing...
18 KB (2,060 words) - 10:53, 18 August 2024
hemoglobin, cytochrome (see high-valent iron), and catalase. The average adult human contains about 0.005% body weight of iron, or about four grams, of which...
44 KB (5,376 words) - 09:18, 1 July 2024
abstracting strong C–H, N–H, and O–H bonds. Cytochrome P450 contains a high-valent iron-oxo which is capable of abstracting hydrogen atoms from strong C–H...
20 KB (1,928 words) - 07:25, 14 June 2024
peroxidase, Compound I is a transient (green) species and contains a high-valent iron species (known as ferryl heme, FeIV) and a porphyrin pi-cation radical...
12 KB (1,255 words) - 22:00, 2 December 2023
aqueous solution saturated with sodium hydroxide.[citation needed] High-valent iron Potassium ferrate Barium ferrate Graham Hill; John Holman (2000). Chemistry...
8 KB (734 words) - 18:06, 2 November 2023
Fenglian; Dionysiou, Dionysios D.; Liu, Hong (2014). "The use of zero-valent iron for groundwater remediation and wastewater treatment: A review". Journal...
7 KB (768 words) - 04:20, 23 May 2023