intermediates or transition states. For certain nucleophiles, solvolysis reactions are classified. Solvolysis involving water is called hydrolysis. Related terms...
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substitution reactions at secondary carbons: Many reactions studied are solvolysis reactions where a solvent molecule (often an alcohol) is the nucleophile...
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same uniform SN1-like mechanism. The solvolysis of several cyclopentyl and steroidal esters show that large solvolysis rates and differences between epimers...
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Young, D. J. Cram (1951). "The Correlation of Solvolysis Rates and the Classification of Solvolysis Reactions Into Mechanistic Categories". Journal...
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VX (nerve agent) (section Solvolysis)
VX with concentrated aqueous sodium hydroxide results in two competing solvolysis reactions: cleavage of either the P–O or P–S esters. Although the P–S...
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also act as nucleophiles, and the process is known as solvolysis. The Y scale correlates solvolysis reaction rates of any solvent (k) with that of a standard...
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Polymer degradation Proteolysis Saponification Sol–gel polymerisation Solvolysis Thermal hydrolysis IUPAC, Compendium of Chemical Terminology, 2nd ed....
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have been generated in photochemical solvolysis reactions. The figure to the right depicts photochemical solvolysis of vinyl iodonium salt, through heterolytic...
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7-norbornenyl tosylate. The elimination occurs 1011 times faster than the solvolysis of anti-7-norbornyl p-toluenesulfonate. Tosylates are also protecting...
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This generally occurs in highly polar solvents through a process called solvolysis. The positively charged component then reacts with a nucleophile forming...
18 KB (2,090 words) - 20:31, 22 July 2024