Dess–Martin periodinane (DMP) is a chemical reagent used in the Dess–Martin oxidation, oxidizing primary alcohols to aldehydes and secondary alcohols...
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Dess–Martin periodinane. It is named after the American chemists Daniel Benjamin Dess and James Cullen Martin who developed the periodinane reagent in...
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has more than 8 valence electrons. The λ5-iodanes such as the Dess-Martin periodinane have square pyramidal geometry with 4 heteroatoms in basal positions...
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Dess may refer to : Dess–Martin periodinane, a chemical reagent used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones Albert...
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2-Iodoxybenzoic acid (category Periodinanes)
both the Swern and Dess–Martin oxidation protocols. Boeckman, R. K. Jr.; Shao, P.; Mullins, J. J. (2000). "Dess–Martin periodinane: 1,1,1-Triacetoxy-1...
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permanganate or a Cr(VI) compound. Milder conditions make use of the Dess–Martin periodinane or the Moffatt–Swern methods. Many other methods have been developed...
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oxidation methods such as pyridinium chlorochromate (PCC) and Dess–Martin periodinane is that secondary alcohols are oxidized much faster than primary...
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most common uses is as a precursor for the preparation of IBX and Dess–Martin periodinane, both used as mild oxidants. 2-Iodobenzoic acid can be synthesized...
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Parikh–Doering oxidation Albright-Goldman oxidation Corey–Kim oxidation Dess–Martin periodinane oxidation Ley oxidation (TPAP oxidation) TEMPO oxidation Omura...
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such are the hypervalent organoiodine compounds (i.e., IBX acid, Dess–Martin periodinane), although these often also oxidize the α position. A Lux-Flood...
30 KB (3,074 words) - 15:22, 14 October 2024