In organic chemistry, hydrovinylation is the formal insertion of an alkene into the C-H bond of ethylene (H2C=CH2): CH2=CHR + CH2=CH2 → CH3−CHR−CH=CH2...
7 KB (805 words) - 20:57, 21 July 2024
stereoselective synthesis. Major research areas include: Asymmetric Hydrovinylation RajanBabu developed methodology surrounding C-C bond formation via...
17 KB (1,735 words) - 01:24, 30 June 2022
process: CH2=CH2 + CH3CH=CHCH3 → 2 CH2=CHCH3 Transition metal catalyzed hydrovinylation is another important alkene synthesis process starting from alkene...
48 KB (5,122 words) - 23:58, 18 July 2024
solid acid catalysts: C2H4 + H2O → CH3CH2OH Ethylene is dimerized by hydrovinylation to give n-butenes using processes licensed by Lummus or IFP. The Lummus...
36 KB (3,232 words) - 01:36, 1 August 2024
hemilabile phosphane ligand compared to a very similar non-labile ligand. Hydrovinylation (olefin dimerisation), which is typically difficult to carry out enantioselectively...
7 KB (834 words) - 14:26, 20 November 2023
Bhalla, G.; Oxgaard, J.; Goddard, W. A.; Periana, Roy A. (2005). "Hydrovinylation of Olefins Catalyzed by an Iridium Complex via CH Activation" (PDF)...
25 KB (2,762 words) - 21:04, 12 August 2024
(2008). "(R)-3-Methyl-3-Phenyl-1-Pentene via Catalytic Asymmetric Hydrovinylation". Org. Synth. 85: 248–266. doi:10.15227/orgsyn.085.0248. PMC 2723857...
11 KB (1,061 words) - 05:49, 25 June 2024
Hydroalkoxylation (also known as hydroetherification) Hydrohalogenation Hydrovinylation (including hydroarylation and olefin dimerization and others) Hydroacylation...
2 KB (216 words) - 15:58, 6 April 2023
widely available vinyl acetate: ROH + CH2=CHOAc → ROCH=CH2 + HOAc Hydrovinylation, ethylene adds "across" an alkene double bond Hamilton, James; Sarlah...
6 KB (602 words) - 21:23, 21 July 2024
(2008). "(R)-3-methyl-3-phenyl-1-pentene Via Catalytic Asymmetric Hydrovinylation". Org. Synth. 85: 248–266. doi:10.15227/orgsyn.085.0248. PMC 2723857...
12 KB (1,344 words) - 06:32, 27 April 2024