• Oxophilicity is the tendency of certain chemical compounds to form oxides by hydrolysis or abstraction of an oxygen atom from another molecule, often from...
    5 KB (583 words) - 06:47, 15 January 2024
  • Thumbnail for Titanium tetrachloride
    occasional use in organic synthesis, capitalizing on its Lewis acidity, its oxophilicity, and the electron-transfer properties of its reduced titanium halides...
    19 KB (1,732 words) - 00:16, 20 June 2024
  • Thumbnail for Zirconyl chloride
    centers. The chloride anions are not ligands, consistent with the high oxophilicity of Zr(IV). The salt crystallizes as tetragonal crystals. Zirconyl acetate...
    3 KB (189 words) - 17:53, 29 December 2023
  • rationalization of ambident reactivity of organic compounds. Acid-base reaction Oxophilicity Jolly, W. L. (1984). Modern Inorganic Chemistry. New York: McGraw-Hill...
    19 KB (2,129 words) - 10:55, 3 October 2024
  • Thumbnail for Organotitanium chemistry
    Titanium is characteristically oxophilic, which recommends the use of air-free techniques. On the other hand, high oxophilicity means that titanium alkyls...
    18 KB (1,866 words) - 09:45, 4 November 2023
  • compounds. Degassing Preparation of stable carbenes Ocean deoxygenation Oxophilicity Sheldon, Roger A. (2014). "Green and sustainable manufacture of chemicals...
    6 KB (582 words) - 19:37, 27 February 2024
  • Thumbnail for Amide
    Bischler–Napieralski reaction Cyclic aryl imine POCl3, SOCl2, etc. Tautomeric chlorination Imidoyl chloride Oxophilic halogenating agents, e.g. COCl2 or SOCl2...
    24 KB (2,322 words) - 01:44, 6 September 2024
  • Thumbnail for Tebbe's reagent
    the Wittig reagent, the reactivity appears to be driven by the high oxophilicity of Ti(IV). The Schrock carbene (1) reacts with carbonyl compounds (2)...
    10 KB (907 words) - 21:15, 3 August 2023
  • Thumbnail for McMurry reaction
    the pinacolate, which yields the alkene, this second step exploits the oxophilicity of titanium. Several mechanisms have been discussed for this reaction...
    7 KB (758 words) - 22:34, 27 September 2024
  • Reactions of anhydrous iron(III) chloride reflect its description as both oxophilic and a hard Lewis acid. Myriad manifestations of the oxophiliicty of iron(III)...
    39 KB (3,874 words) - 06:52, 16 October 2024