Nucleophilic epoxidation is the formation of epoxides from electron-deficient double bonds through the action of nucleophilic oxidants. Nucleophilic epoxidation...
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Epoxide (redirect from Epoxidation)
Katsuki, T.; Sharpless, K. B. (1980). "The first practical method for asymmetric epoxidation". J. Am. Chem. Soc. 102 (18): 5974–5976. doi:10.1021/ja00538a077...
22 KB (2,324 words) - 21:50, 25 August 2024
The Shi epoxidation is a chemical reaction described as the asymmetric epoxidation of alkenes with oxone (potassium peroxymonosulfate) and a fructose-derived...
10 KB (1,183 words) - 20:37, 22 July 2024
The Juliá–Colonna epoxidation is an asymmetric poly-leucine catalyzed nucleophilic epoxidation of electron deficient olefins in a triphasic system. The...
20 KB (2,152 words) - 16:39, 26 April 2024
substrate, reagent, catalyst or environment. Asymmetric induction is a key element in asymmetric synthesis. Asymmetric induction was introduced by Hermann Emil...
29 KB (3,680 words) - 11:33, 19 September 2024
Johnson–Corey–Chaykovsky reaction (category Epoxidation reactions)
PMID 14649793. Aggarwal, V. K.; Winn, C. L. (2004). "Catalytic, Asymmetric Sulfur Ylide-Mediated Epoxidation of Carbonyl Compounds: Scope, Selectivity, and Applications...
22 KB (2,314 words) - 16:34, 26 September 2024
days, and the catalyst is not recyclable. However, the Sharpless asymmetric epoxidation kinetic resolution remains one of the most effective synthetic kinetic...
57 KB (6,914 words) - 13:54, 30 July 2024
; Frohn, M.; Zhang, J.; Shi, Y. (1997). "An Efficient Catalytic Asymmetric Epoxidation Method". J. Am. Chem. Soc. 119 (46): 11224–11235. doi:10.1021/ja972272g...
19 KB (2,321 words) - 12:01, 2 March 2024
Stilbene undergoes reactions typical of alkenes. Trans-stilbene undergoes epoxidation with peroxymonophosphoric acid, H3PO5, producing a 74% yield of trans-stilbene...
21 KB (1,849 words) - 23:26, 17 July 2024
Sharpless asymmetric dihydroxylation Sharpless epoxidation Sharpless oxyamination or aminohydroxylation Shenck ene reaction Shi epoxidation Shiina esterification...
38 KB (3,423 words) - 21:05, 20 August 2024