In organosulfur chemistry, sulfenamides (also spelled sulphenamides) are a class of organosulfur compounds characterized by the general formula R−S−N(−R)2...
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Silver acetate (section Sulfenamide synthesis)
transformations in organic synthesis. Silver acetate is used to prepare sulfenamides from disulfides and secondary amines: R2NH + AgOAc + (RS)2 → R2NSR +...
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intermediate in synthesis of other organic compounds. It is the precursor to sulfenamide-based reagents used as accelerators for vulcanization. The amine itself...
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S-nitrosotriphenylmethanethiol (Ph3CSNO), tritylsulfenyl chloride (Ph3CSCl), and trityl sulfenamide (Ph3CSNH2). Tetraphenylmethane Triphenylmethanol Triphenylmethyl chloride...
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accelerating and mostly consist of thiazoles, often derivatised with sulfenamide groups. The principal compound is 2-mercaptobenzothiazole (MBT), which...
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cysteines accessible from the luminar surface of the enzyme, a tetracyclic sulfenamide. This is a planar molecule thus any enantiomer of a PPI loses stereospecifity...
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S2CID 115671283. Ducháček, Vratislav; Kuta, Antonín (October 1986). "Long-time sulfenamide-accelerated sulfur vulcanization of natural rubber/chlorobutyl rubber...
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both enantiomers are converted to achiral products (sulfenic acid and sulfenamide configurations) which react with a cysteine group in H+/K+ ATPase, thereby...
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residues. After being activated by gastric (stomach) acid to a reactive sulfenamide intermediate, rabeprazole permanently binds the cysteine residues, forming...
67 KB (6,230 words) - 19:32, 19 October 2024
tert-Butylamine is used as an intermediate in the preparation of the sulfenamides such as N-tert-butyl-2-benzothiazylsulfenamide and...
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