(redox) non-innocent ligand is a ligand in a metal complex where the oxidation state is not clear. Typically, complexes containing non-innocent ligands are...
15 KB (1,728 words) - 12:20, 31 January 2024
non-innocent ligands, the ligand is bonded to metals via conventional bonds, but the ligand is also redox-active. In the following table the ligands are...
35 KB (3,307 words) - 12:53, 22 September 2024
Diiminopyridine (category Tridentate ligands)
fashion, forming pincer complexes. Diiminopyridines are notable as non-innocent ligand that can assume more than one oxidation state. Complexes of DIPs...
11 KB (1,250 words) - 10:03, 1 August 2024
conformation. The extremities of the two ligands are slightly distorted outwards. The complex features a non-innocent ligand, in the sense that the macrocycles...
16 KB (1,801 words) - 11:58, 24 May 2024
metal ions that can exchange their oxidation state with their ligands (see non-innocent ligand). One of the first instances was a cobalt bis(quinone) complex...
5 KB (506 words) - 13:08, 11 August 2023
sulfur atoms are equivalent in this square-shaped molecule. when a non-innocent ligand is present, of hidden or unexpected redox properties that could otherwise...
46 KB (8,729 words) - 23:27, 12 October 2024
"dithiolene", i.e. a chelating alkene-1,2-dithiolate. It is a prototypical non-innocent ligand in coordination chemistry. Several complexes are known, such as Ni(mnt)2]2−...
4 KB (247 words) - 20:36, 23 May 2024
Diimine (redirect from Diimine ligand)
glyoxal. 2,2'-Bipyridine is a 1,2-diimine. 1,2-Diketimines are “non-innocent ligands”, akin to the dithiolenes. For example, acetylacetone (2,4-pentanedione)...
5 KB (529 words) - 04:10, 15 August 2024
basic ligand). The ligand can also be redox non-innocent to facilitate reactions that the metal would otherwise be unable to activate. The ligand can act...
22 KB (2,601 words) - 20:40, 22 July 2024
Wolfgang (2012). "The Shrinking World of Innocent Ligands: Conventionaland Non‐Conventional Redox‐Active Ligands". European Journal of Inorganic Chemistry...
7 KB (724 words) - 07:47, 24 July 2023