Thiophosgene is a red liquid with the formula CSCl2. It is a molecule with trigonal planar geometry. There are two reactive C–Cl bonds that allow it to...
6 KB (490 words) - 21:04, 21 August 2024
Often, thiocarbonyldiimidazole is used instead of thiophosgene as shown above, since thiophosgene has a similar toxicity profile as phosgene, whereas...
3 KB (376 words) - 16:01, 19 August 2023
inhalation. TFD can be produced by reaction of perchloromethyl mercaptan or thiophosgene with sodium fluoride. TFD is extremely toxic by inhalation. TFD is a...
2 KB (150 words) - 14:09, 29 April 2023
commercially available but can also be prepared via the reaction of thiophosgene with two equivalents of imidazole. The imidazole groups on TCDI can be...
2 KB (198 words) - 11:38, 11 August 2024
contaminating the Ohio River. Carbonyl bromide Carbonyl fluoride Oxalyl chloride Thiophosgene Thionyl chloride Perfluoroisobutene Bis(trifluoromethyl) disulfide Merck...
30 KB (3,150 words) - 01:09, 25 August 2024
Cl2 → CCl4 + S2Cl2 This conversion proceeds via the intermediacy of thiophosgene, CSCl2. CS2 is a ligand for many metal complexes, forming pi complexes...
29 KB (2,572 words) - 04:41, 21 August 2024
S2Cl2 also arises from the chlorination of CS2 as in the synthesis of thiophosgene or carbon tetrachloride. S2Cl2 hydrolyzes to sulfur dioxide and elemental...
9 KB (751 words) - 23:40, 21 July 2024
{2CCl4 + 2CO -> 2COCl2 + C2Cl4}}} Reaction with hydrogen sulfide gives thiophosgene: CCl 4 + H 2 S ⟶ CCl 2 S + 2 HCl {\displaystyle {\ce {CCl4 + H2S -> CCl2S...
48 KB (5,021 words) - 06:26, 19 August 2024
+ COCl2 → PhC(S)Cl + HCl + COS The most common thioacyl chloride is thiophosgene. Hermann Staudinger; Siegwart, J. (1920). "Ueber Thiobenzoylchlorid"...
2 KB (169 words) - 19:02, 16 October 2023
chloride – TlCl Thallium(III) chloride – TlCl3 Thionyl chloride – SOCl2 Thiophosgene – CSCl2 Thorium(IV) chloride – ThCl4 Thulium(III) chloride – TmCl3 Tin(II)...
119 KB (8,729 words) - 06:43, 23 August 2024