• Thumbnail for Anomeric effect
    organic chemistry, the anomeric effect or Edward-Lemieux effect (after J. T. Edward and Raymond Lemieux) is a stereoelectronic effect that describes the tendency...
    19 KB (2,539 words) - 18:53, 1 August 2024
  • Anomer (redirect from Anomeric carbon)
    the anomeric centre and the anomeric reference atom, hence they are relative stereodescriptors. The anomeric centre in hemiacetals is the anomeric carbon...
    8 KB (883 words) - 16:45, 30 September 2024
  • through a process known as mutarotation. The anomeric effect more accurately called the endo-anomeric effect is the propensity for heteroatoms at C-1 to...
    10 KB (1,156 words) - 18:55, 13 April 2024
  • Thumbnail for Gauche effect
    conformer, rather than the anti-diaxial conformer, in more polar solvents. Anomeric effect Floris Akkerman; Jürgen Buschmann; Dieter Lentz; Peter Luger; Eva Rödel...
    7 KB (865 words) - 08:42, 22 May 2024
  • Thumbnail for Stereoisomerism
    Retrieved 2022-08-09. "Anomer - an overview | ScienceDirect Topics". "Anomeric Effect - an overview | ScienceDirect Topics". Ashenhurst, James (2022-08-03)...
    16 KB (1,641 words) - 13:48, 2 August 2024
  • Thumbnail for Dimethoxymethane
    this effect, which has great interest in carbohydrate chemistry, dimethoxymethane is often used for theoretical studies of the anomeric effect. Industrially...
    7 KB (541 words) - 15:59, 20 August 2024
  • Thumbnail for Raymond Lemieux
    synthesis of sucrose. His contributions include the discovery of the anomeric effect and the development of general methodologies for the synthesis of saccharides...
    10 KB (861 words) - 21:54, 27 October 2024
  • Hyperconjugation can be used to explain phenomena such as the gauche effect and anomeric effect. Orbital symmetry is important when dealing with orbitals that...
    8 KB (1,083 words) - 13:03, 7 March 2024
  • Thumbnail for Glucose
    The ratio would be α:β 11:89 if it were not for the influence of the anomeric effect. Mutarotation is considerably slower at temperatures close to 0 °C...
    121 KB (12,789 words) - 20:45, 27 October 2024
  • Thumbnail for Hyperconjugation
    chemical phenomena, including the anomeric effect, the gauche effect, the rotational barrier of ethane, the beta-silicon effect, the vibrational frequency of...
    20 KB (2,394 words) - 12:04, 1 May 2024