organic chemistry, the anomeric effect or Edward-Lemieux effect (after J. T. Edward and Raymond Lemieux) is a stereoelectronic effect that describes the tendency...
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Anomer (redirect from Anomeric carbon)
the anomeric centre and the anomeric reference atom, hence they are relative stereodescriptors. The anomeric centre in hemiacetals is the anomeric carbon...
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Carbohydrate conformation (section Anomeric effect)
through a process known as mutarotation. The anomeric effect more accurately called the endo-anomeric effect is the propensity for heteroatoms at C-1 to...
10 KB (1,156 words) - 18:55, 13 April 2024
Retrieved 2022-08-09. "Anomer - an overview | ScienceDirect Topics". "Anomeric Effect - an overview | ScienceDirect Topics". Ashenhurst, James (2022-08-03)...
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Hyperconjugation can be used to explain phenomena such as the gauche effect and anomeric effect. Orbital symmetry is important when dealing with orbitals that...
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conformer, rather than the anti-diaxial conformer, in more polar solvents. Anomeric effect Floris Akkerman; Jürgen Buschmann; Dieter Lentz; Peter Luger; Eva Rödel...
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synthesis of sucrose. His contributions include the discovery of the anomeric effect and the development of general methodologies for the synthesis of saccharides...
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this effect, which has great interest in carbohydrate chemistry, dimethoxymethane is often used for theoretical studies of the anomeric effect. Industrially...
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The ratio would be α:β 11:89 if it were not for the influence of the anomeric effect. Mutarotation is considerably slower at temperatures close to 0 °C...
121 KB (12,794 words) - 10:50, 6 August 2024
well-known interactions. These include important phenomena such as the anomeric effect and hyperconjugation. It is important to note that stereoelectronic...
23 KB (2,834 words) - 09:22, 27 October 2023