Cyanometallates or cyanometalates are a class of coordination compounds, most often consisting only of cyanide ligands. Most are anions. Cyanide is a highly...
16 KB (1,431 words) - 22:57, 17 June 2024
ligands H− hydride B2H6 CN− cyanide approx. Fe7(CN)18 (prussian blue), see cyanometalate PPh−2 diphenylphosphide see transition metal phosphido complexes...
8 KB (844 words) - 15:08, 6 July 2023
K4[Mo(CN)8]. A yellow light-sensitive solid, it is the potassium salt of the cyanometalate with the coordination number eight. The complex anion consists of a...
5 KB (398 words) - 12:55, 19 May 2024
ferricyanide ((FeIII(CN)6)3−) are particularly stable and non-toxic polymeric cyanometalates due to the strong iron coordination to cyanide ions. Although cyanide...
45 KB (4,831 words) - 13:32, 14 August 2024
η2-nitrile ligands are intermediates that preceded oxidative addition. Cyanometalate – coordination compounds containing cyanide ligands (coordinating via...
19 KB (1,900 words) - 12:29, 7 June 2024
electron-rich species Fe2(CNEt)9, νC≡N = 2060, 1920, 1701, 1652 cm−l. Cyanometalate - coordination compounds containing cyanide ligands (coordinating via...
19 KB (1,823 words) - 13:48, 15 July 2024