at 457.5, 325, and 239 nm. The nitrito has maxima at 486, 330, and 220 nm. Their IR spectra also differ. The nitrito isomer absorbs at 1460 and 1065 cm−1...
4 KB (438 words) - 11:14, 18 March 2024
Transition metal nitrite complex (redirect from Nitrito complex)
[(NH3)5Co−ONO]2+, referred to as N-nitrito and O-nitrito, respectively. These two forms are sometimes called nitro and nitrito. These isomers can be interconverted...
9 KB (1,050 words) - 15:50, 30 May 2024
nitro ligand is bound through nitrogen. In the red linkage isomer, the nitrito is bound through one oxygen atom. The O-bonded isomer is often written...
3 KB (347 words) - 06:43, 25 July 2023
bonded to an oxygen atom that in turn usually is bonded to a carbon atom (nitrito group). There are many major industrial applications of nitration in the...
9 KB (1,031 words) - 18:06, 4 September 2023
L.; Hitchman, M. A. (October 1964). "Studies of Nitro and Nitrito Complexes. I. Some Nitrito Complexes of Nickel(II)". Inorganic Chemistry. 3 (10): 1389–1394...
8 KB (771 words) - 20:56, 23 September 2023
(bonded from the nitrogen) and nitrito (bonded from an oxygen). Nitro-nitrito isomerism is common, where the nitrito form is usually less stable. Nitric...
105 KB (12,223 words) - 08:00, 14 August 2024
trianionic coordination complex. In the anion, cobalt is bound by six nitrito ligands, the overall complex having octahedral molecular geometry. The...
4 KB (258 words) - 04:29, 28 December 2023
[O−CO−CO−O]2− dianionic bidentate Water (aqua) O−H2 neutral monodentate Nitrite (nitrito) O−N−O− monoanionic monodentate ambidentate (see also nitro) Isothiocyanate...
35 KB (3,307 words) - 13:02, 16 February 2024
the ability of silicon in its crystal phase to coordinate to two oxygen nitrito groups in addition to regular coordination to the four carbon atoms. This...
4 KB (433 words) - 20:48, 9 November 2023