chemistry, an iminium cation is a polyatomic ion with the general structure [R1R2C=NR3R4]+. They are common in synthetic chemistry and biology. Iminium cations...
6 KB (621 words) - 05:09, 22 August 2024
reactions, the anion is PO2Cl2−. The iminium cation [(CH3)2N=CHCl]+ is the reactive component of interest. This iminium species is a derivative of the imidoyl...
3 KB (207 words) - 19:58, 30 September 2023
Bis(triphenylphosphine)iminium chloride is the chemical compound with the formula [((C6H5)3P)2N]Cl, often abbreviated [(Ph3P)2N]Cl, where Ph is phenyl...
7 KB (591 words) - 06:48, 22 June 2024
pathway. The driving force for this reaction is the electrophilicity of the iminium ion generated from the condensation of the aldehyde and amine under acid...
11 KB (1,182 words) - 03:14, 23 January 2024
compounds to form iminium ions is often unfavorable, sometimes requiring harsh dehydrating conditions. Thus, alternative methods for iminium ion generation...
50 KB (6,209 words) - 14:32, 1 November 2024
good leaving group for formation of the iminium ion, in accordance with its usage in iminium ion generation. Iminium ion generation from cyanomethyl groups...
50 KB (5,704 words) - 20:45, 22 July 2024
of an active enamine nucleophile) or iminium catalysis (by forming catalytic quantities of an activated iminium electrophile). This mechanism is typical...
17 KB (1,721 words) - 15:08, 13 November 2024
4-chlorophenyl azide can also lead to the useful transformation of the iminium ion. The iminium ion is important in organic syntheses because it reacts similarly...
11 KB (1,183 words) - 17:58, 7 September 2024
An intermolecular formal [3+3] cycloaddition between an cyclic iminium chloride and cyclopentenone....
11 KB (1,261 words) - 17:18, 22 January 2024
Azomethine ylide (section From imines and iminiums)
Azomethine ylides are nitrogen-based 1,3-dipoles, consisting of an iminium ion next to a carbanion. They are used in 1,3-dipolar cycloaddition reactions...
18 KB (1,988 words) - 01:46, 19 April 2024