• Thumbnail for Iminium
    chemistry, an iminium cation is a polyatomic ion with the general structure [R1R2C=NR3R4]+. They are common in synthetic chemistry and biology. Iminium cations...
    6 KB (621 words) - 05:09, 22 August 2024
  • Thumbnail for Vilsmeier reagent
    reactions, the anion is PO2Cl2−. The iminium cation [(CH3)2N=CHCl]+ is the reactive component of interest. This iminium species is a derivative of the imidoyl...
    3 KB (207 words) - 19:58, 30 September 2023
  • Thumbnail for Bis(triphenylphosphine)iminium chloride
    Bis(triphenylphosphine)iminium chloride is the chemical compound with the formula [((C6H5)3P)2N]Cl, often abbreviated [(Ph3P)2N]Cl, where Ph is phenyl...
    7 KB (591 words) - 06:48, 22 June 2024
  • pathway. The driving force for this reaction is the electrophilicity of the iminium ion generated from the condensation of the aldehyde and amine under acid...
    11 KB (1,182 words) - 03:14, 23 January 2024
  • Thumbnail for Photoredox catalysis
    compounds to form iminium ions is often unfavorable, sometimes requiring harsh dehydrating conditions. Thus, alternative methods for iminium ion generation...
    50 KB (6,209 words) - 14:32, 1 November 2024
  • good leaving group for formation of the iminium ion, in accordance with its usage in iminium ion generation. Iminium ion generation from cyanomethyl groups...
    50 KB (5,704 words) - 20:45, 22 July 2024
  • Thumbnail for Organocatalysis
    of an active enamine nucleophile) or iminium catalysis (by forming catalytic quantities of an activated iminium electrophile). This mechanism is typical...
    17 KB (1,721 words) - 15:08, 13 November 2024
  • Thumbnail for 4-Chlorophenyl azide
    4-chlorophenyl azide can also lead to the useful transformation of the iminium ion. The iminium ion is important in organic syntheses because it reacts similarly...
    11 KB (1,183 words) - 17:58, 7 September 2024
  • An intermolecular formal [3+3] cycloaddition between an cyclic iminium chloride and cyclopentenone....
    11 KB (1,261 words) - 17:18, 22 January 2024
  • Thumbnail for Azomethine ylide
    Azomethine ylides are nitrogen-based 1,3-dipoles, consisting of an iminium ion next to a carbanion. They are used in 1,3-dipolar cycloaddition reactions...
    18 KB (1,988 words) - 01:46, 19 April 2024