• In organic chemistry, the Swern oxidation, named after Daniel Swern, is a chemical reaction whereby a primary or secondary alcohol (−OH) is oxidized to...
    9 KB (1,019 words) - 17:16, 26 December 2023
  • pyridinium chlorochromate) or dimethyl sulfoxide (e.g. Swern oxidation) or Dess–Martin oxidation due to its use of relatively mild and non-toxic reagents...
    12 KB (1,250 words) - 17:28, 13 May 2022
  • Alcohol oxidation is a collection of oxidation reactions in organic chemistry that convert alcohols to aldehydes, ketones, carboxylic acids, and esters...
    15 KB (1,706 words) - 18:54, 31 October 2024
  • displaced by the Swern oxidation, which also uses DMSO as an oxidant in the presence of an electrophilic activator. Swern oxidations tend to give higher...
    3 KB (338 words) - 17:57, 30 May 2023
  • chemist Choung Un Kim. Although the Corey–Kim oxidation possesses the distinctive advantage over Swern oxidation of allowing an operation above –25 °C, it...
    5 KB (481 words) - 23:40, 9 November 2024
  • Swern is a surname. Notable people with the surname include: Daniel Swern (1916–1982), American chemist Swern oxidation, an organic chemical reaction...
    282 bytes (74 words) - 03:16, 20 September 2024
  • Thumbnail for Dess–Martin periodinane
    Parikh–Doering oxidation Albright-Goldman oxidation Swern oxidation Corey–Kim oxidation Ley oxidation (TPAP oxidation) TEMPO oxidation Dess, D. B.; Martin, J. C. (1983)...
    12 KB (1,197 words) - 03:33, 24 June 2024
  • Thumbnail for N,N-Diisopropylethylamine
    Although triethylamine is traditionally employed as the hindered base in Swern oxidations, the structurally similar DIPEA can be used instead, as exemplified...
    10 KB (809 words) - 11:18, 15 January 2024
  • Thumbnail for Aldehyde
    pre-oxidized substrates: various sulfoxides (e.g. the Swern oxidation), or amine oxides (e.g., the Ganem oxidation). Sterically-hindered nitroxyls (i.e., TEMPO)...
    30 KB (3,075 words) - 07:44, 12 November 2024
  • to the corresponding ketone). Selective oxidation of alcohols to aldehydes requires circumventing over-oxidation to the carboxylic acid. One popular approach...
    6 KB (729 words) - 16:41, 12 June 2023