Isotopes of berkelium
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Berkelium (97Bk) is an artificial element, and thus a standard atomic weight cannot be given. Like all artificial elements, it has no stable isotopes. The first isotope to be synthesized was 243Bk in 1949. There are twenty known radioisotopes, from 233Bk and 233Bk to 253Bk (except 235Bk and 237Bk), and six nuclear isomers. The longest-lived isotope is 247Bk with a half-life of 1,380 years.
List of isotopes
[edit]Nuclide [n 1] | Z | N | Isotopic mass (Da)[3] [n 2][n 3] | Half-life[1] | Decay mode[1] [n 4] | Daughter isotope | Spin and parity[1] [n 5][n 6] | ||||||||||||
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Excitation energy[n 6] | |||||||||||||||||||
233Bk | 97 | 136 | 233.05665(25)# | 40(30) s | α | 229Am | 3/2-# | ||||||||||||
β+? | 233Cm | ||||||||||||||||||
234Bk | 97 | 137 | 234.05732(16)# | 20(5) s | α (>80%) | 230Am | 3-# | ||||||||||||
β+ (<20%) | 234Cm | ||||||||||||||||||
β+, SF?[4] | (various) | ||||||||||||||||||
236Bk | 97 | 139 | 236.05748(39)# | 26(10) s | β+ (99.96%) | 236Cm | 4+# | ||||||||||||
β+, SF (0.04%) | (various) | ||||||||||||||||||
α? | 232Am | ||||||||||||||||||
238Bk | 97 | 141 | 238.05820(28)# | 2.40(8) min | β+ (99.95%) | 238Cm | 1# | ||||||||||||
β+, SF (0.048%) | (various) | ||||||||||||||||||
α? | 234Am | ||||||||||||||||||
239Bk | 97 | 142 | 239.05824(22)# | 100# s | β+ | 239Cm | (7/2+) | ||||||||||||
α? | 235Am | ||||||||||||||||||
SF? | (various) | ||||||||||||||||||
240Bk | 97 | 143 | 240.05976(16)# | 4.8(8) min | β+? | 240Cm | 7−# | ||||||||||||
β+, SF (0.0020%) | (various) | ||||||||||||||||||
α? | 236Am | ||||||||||||||||||
241Bk | 97 | 144 | 241.06010(18)# | 4.6(4) min | β+? | 241Cm | (7/2+) | ||||||||||||
α? | 237Am | ||||||||||||||||||
242Bk | 97 | 145 | 242.06198(22)# | 7.0(13) min | β+ | 242Cm | 3+# | ||||||||||||
β+, SF (<3×10−5%) | (various) | ||||||||||||||||||
α? | 238Am | ||||||||||||||||||
242mBk | 2000(200)# keV | 600(100) ns | SF | (various) | |||||||||||||||
IT? | 242Bk | ||||||||||||||||||
243Bk | 97 | 146 | 243.0630059(49) | 4.6(2) h | β+ (99.85%) | 243Cm | 3/2− | ||||||||||||
α (.15%) | 239Am | ||||||||||||||||||
244Bk | 97 | 147 | 244.065179(15) | 5.02(3) h | β+? | 244Cm | 4− | ||||||||||||
α (0.006%) | 240Am | ||||||||||||||||||
244mBk | 1500(500)# keV | 820(60) ns | SF | (various) | |||||||||||||||
IT? | 244Bk | ||||||||||||||||||
245Bk | 97 | 148 | 245.0663598(19) | 4.95(3) d | EC (99.88%) | 245Cm | 3/2− | ||||||||||||
α (.12%) | 241Am | ||||||||||||||||||
246Bk | 97 | 149 | 246.068671(64) | 1.80(2) d | β+ | 246Cm | 2(−) | ||||||||||||
α? | 242Am | ||||||||||||||||||
247Bk | 97 | 150 | 247.0703059(56) | 1.38(25)×103 y | α | 243Am | 3/2− | ||||||||||||
SF? | (various) | ||||||||||||||||||
248Bk | 97 | 151 | 248.073142(54) | >9 y | α? | 244Am | 6+# | ||||||||||||
EC? | 248Cm | ||||||||||||||||||
248mBk | −20(50) keV[n 7] | 23.7(2) h | β− (70%) | 248Cf | 1(−) | ||||||||||||||
EC (30%) | 248Cm | ||||||||||||||||||
α? | 244Am | ||||||||||||||||||
249Bk | 97 | 152 | 249.0749831(13) | 327.2(3) d | β− | 249Cf | 7/2+ | ||||||||||||
α (.00145%) | 245Am | ||||||||||||||||||
SF (4.7×10−8%) | (various) | ||||||||||||||||||
249mBk | 8.777(14) keV | 300 μs | IT | 249Bk | 3/2− | ||||||||||||||
250Bk | 97 | 153 | 250.0783172(31) | 3.212(5) h | β− | 250Cf | 2− | ||||||||||||
250m1Bk | 35.59(10) keV | 29(1) μs | IT | 250Bk | 4+ | ||||||||||||||
250m2Bk | 85.6(16) keV | 213(8) μs | IT | 250Bk | 7+ | ||||||||||||||
251Bk | 97 | 154 | 251.080761(12) | 55.6(11) min | β− | 251Cf | (3/2−) | ||||||||||||
251mBk | 35.5(13) keV | 58(4) μs | IT | 251Bk | (7/2+) | ||||||||||||||
252Bk | 97 | 155 | 252.08431(22)# | 1.8(5) min | β−? | 252Cf | |||||||||||||
α? | 248Am | ||||||||||||||||||
253Bk | 97 | 156 | 253.08688(39)# | 60# min | β−? | 253Cf | 3/2-# | ||||||||||||
This table header & footer: |
- ^ mBk – Excited nuclear isomer.
- ^ ( ) – Uncertainty (1σ) is given in concise form in parentheses after the corresponding last digits.
- ^ # – Atomic mass marked #: value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
- ^ Modes of decay:
EC: Electron capture SF: Spontaneous fission - ^ ( ) spin value – Indicates spin with weak assignment arguments.
- ^ a b # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
- ^ Order of ground state and isomer is uncertain.[1][5]
Actinides vs fission products
[edit]Actinides[6] by decay chain | Half-life range (a) | Fission products of 235U by yield[7] | ||||||
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4n | 4n + 1 | 4n + 2 | 4n + 3 | 4.5–7% | 0.04–1.25% | <0.001% | ||
228Ra№ | 4–6 a | 155Euþ | ||||||
244Cmƒ | 241Puƒ | 250Cf | 227Ac№ | 10–29 a | 90Sr | 85Kr | 113mCdþ | |
232Uƒ | 238Puƒ | 243Cmƒ | 29–97 a | 137Cs | 151Smþ | 121mSn | ||
248Bk[8] | 249Cfƒ | 242mAmƒ | 141–351 a | No fission products have a half-life | ||||
241Amƒ | 251Cfƒ[9] | 430–900 a | ||||||
226Ra№ | 247Bk | 1.3–1.6 ka | ||||||
240Pu | 229Th | 246Cmƒ | 243Amƒ | 4.7–7.4 ka | ||||
245Cmƒ | 250Cm | 8.3–8.5 ka | ||||||
239Puƒ | 24.1 ka | |||||||
230Th№ | 231Pa№ | 32–76 ka | ||||||
236Npƒ | 233Uƒ | 234U№ | 150–250 ka | 99Tc₡ | 126Sn | |||
248Cm | 242Pu | 327–375 ka | 79Se₡ | |||||
1.53 Ma | 93Zr | |||||||
237Npƒ | 2.1–6.5 Ma | 135Cs₡ | 107Pd | |||||
236U | 247Cmƒ | 15–24 Ma | 129I₡ | |||||
244Pu | 80 Ma | ... nor beyond 15.7 Ma[10] | ||||||
232Th№ | 238U№ | 235Uƒ№ | 0.7–14.1 Ga | |||||
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References
[edit]- ^ a b c d e Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
- ^ Milsted, J.; Friedman, A. M.; Stevens, C. M. (1965). "The alpha half-life of berkelium-247; a new long-lived isomer of berkelium-248". Nuclear Physics. 71 (2): 299. doi:10.1016/0029-5582(65)90719-4.
- ^ Wang, Meng; Huang, W.J.; Kondev, F.G.; Audi, G.; Naimi, S. (2021). "The AME 2020 atomic mass evaluation (II). Tables, graphs and references*". Chinese Physics C. 45 (3): 030003. doi:10.1088/1674-1137/abddaf.
- ^ Kaji, D.; Morimoto, K.; Haba, H.; Ideguchi, E.; Koura, H.; Morita, K. (2016). "Decay Properties of New Isotopes 234Bk and 230Am, and Even–Even Nuclides 234Cm and 230Pu" (PDF). Journal of the Physical Society of Japan. 84 (15002): 015002. Bibcode:2016JPSJ...85a5002K. doi:10.7566/JPSJ.85.015002.
- ^ https://www.nndc.bnl.gov/ensnds/248/Bk/adopted.pdf, NNDC Chart of Nuclides, Adopted Levels for 248Bk.
- ^ Plus radium (element 88). While actually a sub-actinide, it immediately precedes actinium (89) and follows a three-element gap of instability after polonium (84) where no nuclides have half-lives of at least four years (the longest-lived nuclide in the gap is radon-222 with a half life of less than four days). Radium's longest lived isotope, at 1,600 years, thus merits the element's inclusion here.
- ^ Specifically from thermal neutron fission of uranium-235, e.g. in a typical nuclear reactor.
- ^ Milsted, J.; Friedman, A. M.; Stevens, C. M. (1965). "The alpha half-life of berkelium-247; a new long-lived isomer of berkelium-248". Nuclear Physics. 71 (2): 299. Bibcode:1965NucPh..71..299M. doi:10.1016/0029-5582(65)90719-4.
"The isotopic analyses disclosed a species of mass 248 in constant abundance in three samples analysed over a period of about 10 months. This was ascribed to an isomer of Bk248 with a half-life greater than 9 [years]. No growth of Cf248 was detected, and a lower limit for the β− half-life can be set at about 104 [years]. No alpha activity attributable to the new isomer has been detected; the alpha half-life is probably greater than 300 [years]." - ^ This is the heaviest nuclide with a half-life of at least four years before the "sea of instability".
- ^ Excluding those "classically stable" nuclides with half-lives significantly in excess of 232Th; e.g., while 113mCd has a half-life of only fourteen years, that of 113Cd is eight quadrillion years.
- Isotope masses from:
- Audi, Georges; Bersillon, Olivier; Blachot, Jean; Wapstra, Aaldert Hendrik (2003), "The NUBASE evaluation of nuclear and decay properties", Nuclear Physics A, 729: 3–128, Bibcode:2003NuPhA.729....3A, doi:10.1016/j.nuclphysa.2003.11.001
- Half-life, spin, and isomer data selected from the following sources.
- Audi, Georges; Bersillon, Olivier; Blachot, Jean; Wapstra, Aaldert Hendrik (2003), "The NUBASE evaluation of nuclear and decay properties", Nuclear Physics A, 729: 3–128, Bibcode:2003NuPhA.729....3A, doi:10.1016/j.nuclphysa.2003.11.001
- National Nuclear Data Center. "NuDat 2.x database". Brookhaven National Laboratory.
- Holden, Norman E. (2004). "11. Table of the Isotopes". In Lide, David R. (ed.). CRC Handbook of Chemistry and Physics (85th ed.). Boca Raton, Florida: CRC Press. ISBN 978-0-8493-0485-9.