Chloryl fluoride

Chloryl fluoride
Names
	Other names chlorine dioxide fluoride
Identifiers
CAS Number	13637-83-7 ;
3D model (JSmol)	Interactive image;
ChemSpider	123044 ;
PubChem CID	139523;
CompTox Dashboard (EPA)	DTXSID00159769 ;
	InChI InChI=1S/ClFO2/c2-1(3)4 Key: YVRLYFHVJLYEHM-UHFFFAOYSA-N ; InChI=1/ClFO2/c2-1(3)4 Key: YVRLYFHVJLYEHM-UHFFFAOYAO;
	SMILES FCl(=O)=O;
Properties
Chemical formula	ClFO2
Molar mass	86.45 g·mol−1
Density	3.534 g/L
Melting point	−115 °C
Boiling point	−6 °C
Related compounds
Related compounds	Perchloryl fluoride; Chloryl trifluoride
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

Chloryl fluoride is the chemical compound with the formula ClO₂F. It is commonly encountered as side-product in reactions of chlorine fluorides with oxygen sources.^[1] It is the acyl fluoride of chloric acid.

Preparation

ClO₂F was first reported by Schmitz and Schumacher in 1942, who prepared it by the fluorination of ClO₂.^[2] The compound is more conveniently prepared by reaction of sodium chlorate and chlorine trifluoride^[3] and purified by vacuum fractionation, i.e. selectively condensing this species separately from other products. This species is a gas boiling at −6 °C:

6 NaClO₃ + 4 ClF₃ → 6 ClO₂F + 2 Cl₂ + 3 O₂ + 6 NaF

Structure

In contrast to O₂F₂, ClO₂F is a pyramidal molecule. This structure is predicted by VSEPR. The differing structures reflects the greater tendency of chlorine to exist in positive oxidation states with oxygen and fluorine ligands. The related Cl-O-F compound perchloryl fluoride, ClO₃F, is tetrahedral. The related bromine compound bromyl fluoride (BrO₂F) adopts the same structure as ClO₂F, whereas iodyl fluoride (IO₂F) forms a polymeric substance under standard conditions.^[4]

References

^ Christe, K. O.; Wilson, R. D.; Schack, C. J. "Chloryl fluoride" Inorganic Syntheses, 1986, volume 24, pages 3–5. ISBN 0-471-83441-6 https://onlinelibrary.wiley.com/doi/10.1002/9780470132555.ch2
^ Schmitz, H.; Schumacheb, H. J. (1942-04-29). "Über eine neue Reaktion des Chlordioxyds. Die Bildung einer Verbindung der Formel ClO2F". Zeitschrift für anorganische und allgemeine Chemie (in German). 249 (3). Wiley: 238–244. doi:10.1002/zaac.19422490302. ISSN 0863-1786.
^ Wiberg, Egon; Wiberg, Nils; Holleman, A. F. (2001). Inorganic chemistry. San Diego: Academic Press. p. 1797. ISBN 0-12-352651-5. OCLC 48056955.
^ Holleman, A.F.; Wiberg, E.; Wiberg, N. (1995). Lehrbuch der anorganischen Chemie. de Gruyter. p. 501. ISBN 9783110126419. Retrieved 2015-02-20.

External links

WebBook page for ClO2F

[1] Christe, K. O.; Wilson, R. D.; Schack, C. J. "Chloryl fluoride" Inorganic Syntheses, 1986, volume 24, pages 3–5. ISBN 0-471-83441-6 https://onlinelibrary.wiley.com/doi/10.1002/9780470132555.ch2

[2] Schmitz, H.; Schumacheb, H. J. (1942-04-29). "Über eine neue Reaktion des Chlordioxyds. Die Bildung einer Verbindung der Formel ClO2F". Zeitschrift für anorganische und allgemeine Chemie (in German). 249 (3). Wiley: 238–244. doi:10.1002/zaac.19422490302. ISSN 0863-1786.

[3] Wiberg, Egon; Wiberg, Nils; Holleman, A. F. (2001). Inorganic chemistry. San Diego: Academic Press. p. 1797. ISBN 0-12-352651-5. OCLC 48056955.

[google-4] Holleman, A.F.; Wiberg, E.; Wiberg, N. (1995). Lehrbuch der anorganischen Chemie. de Gruyter. p. 501. ISBN 9783110126419. Retrieved 2015-02-20.

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v t e Chlorine compounds
Chlorides and acids	HCl HClO HClO₂ HClO₃ HClO₄ HSO₃Cl BaClF BCl₃ CCl₄ SiCl₄ TiCl₄ C₃H₅Cl
Chlorine fluorides	ClF ClF₃ ClF₅
Chlorine oxides	ClO ClO₂ Cl₂O Cl₂O₂ Cl₂O₃ Cl₂O₄ Cl₂O₅ Cl₂O₆ Cl₂O₇ ClO₄
Chlorine oxyfluorides	ClOF ClOF₃ ClO₂F ClOF₅ (predicted) ClO₂F₃ ClO₃F
Chlorine(I) derivatives	ClNO₃ ClSO₃F ClN₃ Cl₃N

Names

Other names chlorine dioxide fluoride
Identifiers
CAS Number	13637-83-7^Y
3D model (JSmol)	Interactive image
ChemSpider	123044^N
PubChem CID	139523
CompTox Dashboard (EPA)	DTXSID00159769
InChI InChI=1S/ClFO2/c2-1(3)4^N Key: YVRLYFHVJLYEHM-UHFFFAOYSA-N^N InChI=1/ClFO2/c2-1(3)4 Key: YVRLYFHVJLYEHM-UHFFFAOYAO
SMILES FCl(=O)=O
Properties
Chemical formula	ClFO₂
Molar mass	86.45 g·mol⁻¹
Density	3.534 g/L
Melting point	−115 °C
Boiling point	−6 °C
Related compounds
Related compounds	Perchloryl fluoride Chloryl trifluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). N verify (what is ^YN ?) Infobox references