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DeutschCopper(II) oxalate
_Oxalate_Structural_Formula_V1.svg) | |
-oxalat.jpg) | |
| Names | |
|---|---|
| Other names Copper (II) oxalate, cupric oxalate, copper(2+) ethanedioate | |
| Identifiers | |
| |
3D model (JSmol) | |
| ChemSpider | |
| ECHA InfoCard | 100.011.283 |
| EC Number |
|
PubChem CID | |
| UNII | |
| UN number | 3077 |
CompTox Dashboard (EPA) | |
| |
| |
| Properties | |
| CuC 2O 4 | |
| Molar mass | 151.56 |
| Appearance | blue solid |
| Density | 6.57 g/cm3 |
| insoluble | |
Solubility product (Ksp) | 4.43×10−10[1] |
| Hazards | |
| GHS labelling: | |
 [2] | |
| Warning | |
| H302, H302+H312, H312 | |
| P264, P270, P280, P301+P312, P302+P352, P312, P322, P330, P363, P501 | |
| Related compounds | |
Related compounds | Calcium oxalate Sodium oxalate Magnesium oxalate Strontium oxalate Barium oxalate Iron(II) oxalate Iron(III) oxalate |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
Copper(II) oxalate are inorganic compounds with the chemical formula CuC2O4(H2O)x. The value of x can be 0, 0.44, and 1. Two of these species are found as secondary minerals (degradation of minerals), whewellite (monohydrate) and moolooite (0.44 hydrate).[3] The anhydrous compound has been characterized by X-ray crystallography.[4] Many transition metal oxalate complexes are known.
Copper(II) monooxalates are practically insoluble in all solvents. They are coordination polymers.[5]
Synthesis
[edit]Copper(II) oxalate can be produced by precipitation from acidified aqueous copper(II) salts and oxalic acid.[6][7]
- CuSO4 + H2C2O4 + H2O → CuC2O4·H2O + H2SO4
Reactions
[edit]Upon heating to 130 °C, the hydrated copper(II) oxalates convert to the anhydrous cupric oxalate. Further heating at higher temperatures under an atmosphere of hydrogen gives copper metal, suitable as a reagent.[6]
The hydrates bind Lewis bases.
Hydrated copper(II) oxalate reacts with alkali metal oxalates and ammonium oxalate to give bis(oxalato)cuprate:[8]
- CuC2O4)(H2O)x + C2O2−4 → [Cu(C2O4)2]2− + x H2O
Uses
[edit]Copper oxalate is used as a catalyst for organic reactions, as a stabilizer for acetylated polyformaldehyde.[9][10]
Related compounds
[edit]- Cuprous oxalates.[11]
References
[edit]- ^ John Rumble (June 18, 2018). CRC Handbook of Chemistry and Physics (99 ed.). CRC Press. pp. 5–188. ISBN 978-1138561632.
- ^ "Copper oxalate - Substance Information - ECHA". European Chemical Agency. Retrieved 17 June 2021.
- ^ Christensen, Axel Nørlund; Lebech, Bente; Andersen, Niels Hessel; Grivel, Jean-Claude (2014). "The Crystal structure of paramagnetic copper(<SCP>ii</SCP>) oxalate (CuC2O4): Formation and thermal decomposition of randomly stacked anisotropic nano-sized crystallites" (PDF). Dalton Trans. 43 (44): 16754–16768. doi:10.1039/C4DT01689K. PMID 25278188.
- ^ Schmittler, H. (1968). "Zum Strukturprinzip des fehlgeordneten Kupfer(II)-Oxalats CuC2O4·nH2O". Monatsberichte der Deutschen Akademie der Wissenschaften zu Berlin. 10: 581-604.
- ^ "Hazardous Substances Data Bank (HSDB) : 265". National Library of Medicine. Retrieved 17 June 2021.
- ^ a b O. Glemser; R. Sauer (1963). "Copper(II) Sulfide". In G. Brauer (ed.). Handbook of Preparative Inorganic Chemistry, 2nd Ed. Vol. 2pages=1017-1018. NY,NY: Academic Press.
- ^ Gooch, Frank Austin (1909). The precipitation of copper oxalate in analysis. p. 448. OCLC 890741677.
- ^ Kirschner, Stanley; McLean, John A.; Meerman, Gerardine (1960). "Potassium Dioxalatocuprate(II) 2-Hydrate". Inorganic Syntheses. Vol. 6. pp. 1–2. doi:10.1002/9780470132371.ch1. ISBN 978-0-470-13165-7.
- ^ Richardson, H. Wayne (1997). Handbook of Copper Compounds and Applications. CRC Press. p. 84. ISBN 978-0-8247-8998-5.
- ^ Richardson, H. Wayne (2000). "Copper Compounds". Ullmann's Encyclopedia of Industrial Chemistry. doi:10.1002/14356007.a07_567. ISBN 978-3-527-30385-4.
- ^ Royappa, A. Timothy; Royappa, Andrew D.; Moral, Raphael F.; Rheingold, Arnold L.; Papoular, Robert J.; Blum, Deke M.; Duong, Tien Q.; Stepherson, Jacob R.; Vu, Oliver D.; Chen, Banghao; Suchomel, Matthew R.; Golen, James A.; André, Gilles; Kourkoumelis, Nikolaos; Mercer, Andrew D.; Pekarek, Allegra M.; Kelly, Dylan C. (November 2016). "Copper(I) oxalate complexes: Synthesis, structures and surprises". Polyhedron. 119: 563–574. doi:10.1016/j.poly.2016.09.043.