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DeutschFile:Simple aldol reaction.svg
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Summary
| Description | English: A simple overview of the aldol reaction including the aldol condensation. The scheme shows both enol and enolate modes of addition. |
| Date | |
| Source | Own work |
| Author | Krishnavedala |
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LaTeX source code |
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\documentclass[12pt,border=1pt,crop,multi=false,tikz]{standalone} \usepackage[T1]{fontenc} \usepackage[utf8]{inputenc} \usepackage{chemfig,chemmacros} \usepackage{lmodern} \usetikzlibrary{decorations.pathmorphing} \chemsetup[chemformula]{font-shape=sf,format=\sffamily} \renewcommand*{\familydefault}{\sfdefault} \renewcommand*\printatom[1]{\ensuremath{\mathsf{#1}}} \setatomsep{3em} \setdoublesep{.6ex} \setarrowdefault{,1.5,thick} \setbondstyle{thick} \makeatletter \begin{document} \definesubmol\nobond{-[,0.25,,,draw=none]} \schemestart[][north] \chemleft.\subscheme{ \chemname {\chemfig{R-[:30]C(=[2]O)-[:-30]CH_3}} {ENOL mode} \arrow{<=>[catalytic \ch{H+}]} \chemname {\chemfig{R-[:30]C(-[2]OH)=[:-30]CH_2}} {enol} \arrow{<=>[{\chemfig[blue][scale=0.75]{H-[:30]C(=[2]O)-[:-30]R'}}][\parbox{2.25cm}{\footnotesize(reacts in protonated form)}]} \chemname {\chemfig{R-[:30]C(=[2]O)-[:-30]CH_2-[:30] \textcolor{blue}{C}(-[2,,,,blue]\textcolor{blue}{O}(-[:150]H))(-[6,.75,,,blue]\textcolor{blue}{H})-[:-30,,,,blue]\textcolor{blue}{R'}}} {aldol addition product} \arrow(@c4--){0}[-90,.75] \chemfig{R-[:30]C(=[2]O)-[:-30]CH_2-[:30] \textcolor{blue}{C}(-[2,,,1,blue]\textcolor{blue}{O}^\ominus(-[,.5,,,draw=none]M^\oplus))(-[6,.75,,,blue]\textcolor{blue}{H})-[:-30,,,,blue]\textcolor{blue}{R'}} \arrow{<=>[{\chemfig[blue][scale=0.75]{H-[:30]C(=[2]O)-[:-30]R'}}]}[-180] \chemname* {\chemfig{R-[:30]C(-[2,,,1]O^\ominus(-[,.5,,,draw=none]M^\oplus))=[:-30]CH_2}} {enolate} \arrow{<=>[base]}[180] \chemname* {\chemfig{R-[:30]C(=[2]O)-[:-30]CH_3}} {ENOLATE mode} } \chemright\} \arrow{->[$-$\ch{H2O}]} \chemname {\chemfig{R-[:30]C(=[2]O)-[:-30]C(-[6,.25,,,draw=none] H)=[:30] \textcolor{blue}{C}(-[2,,,,blue]\textcolor{blue}{H})-[:-30,,,,blue]\textcolor{blue}{R'}}} {aldol condensation product} \schemestop \end{document} |
Licensing
I, the copyright holder of this work, hereby publish it under the following license:
  | This file is made available under the Creative Commons CC0 1.0 Universal Public Domain Dedication. |
| The person who associated a work with this deed has dedicated the work to the public domain by waiving all of their rights to the work worldwide under copyright law, including all related and neighboring rights, to the extent allowed by law. You can copy, modify, distribute and perform the work, even for commercial purposes, all without asking permission.
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File history
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| Date/Time | Thumbnail | Dimensions | User | Comment | |
|---|---|---|---|---|---|
| current | 15:06, 12 August 2014 | | 895 × 289 (73 KB) | Krishnavedala | {{Information |Description ={{en|1=A simple overview of the aldol reaction including the aldol condensation. The scheme shows both enol and enolate modes of addition.}} |Source ={{own}} |Author... |
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