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DeutschMicrofabrication
Microfabrication is the process of fabricating miniature structures of micrometre scales and smaller. Historically, the earliest microfabrication processes were used for integrated circuit fabrication, also known as "semiconductor manufacturing" or "semiconductor device fabrication". In the last two decades, microelectromechanical systems (MEMS), microsystems (European usage), micromachines (Japanese terminology) and their subfields have re-used, adapted or extended microfabrication methods. These subfields include microfluidics/lab-on-a-chip, optical MEMS (also called MOEMS), RF MEMS, PowerMEMS, BioMEMS and their extension into nanoscale (for example NEMS, for nano electro mechanical systems). The production of flat-panel displays and solar cells also uses similar techniques.
Miniaturization of various devices presents challenges in many areas of science and engineering: physics, chemistry, materials science, computer science, ultra-precision engineering, fabrication processes, and equipment design. It is also giving rise to various kinds of interdisciplinary research.[1] The major concepts and principles of microfabrication are microlithography, doping, thin films, etching, bonding, and polishing.
Fields of use
[edit]Microfabricated devices include:
- integrated circuits (“microchips”) (see semiconductor manufacturing)
- microelectromechanical systems (MEMS) and microoptoelectromechanical systems (MOEMS)
- microfluidic devices (ink jet print heads)
- solar cells
- flat panel displays (see AMLCD and thin-film transistors)
- sensors (microsensors) (biosensors, nanosensors)
- power MEMS, fuel cells, energy harvesters/scavengers
Origins
[edit]Microfabrication technologies originate from the microelectronics industry, and the devices are usually made on silicon wafers even though glass, plastics and many other substrate are in use. Micromachining, semiconductor processing, microelectronic fabrication, semiconductor fabrication, MEMS fabrication and integrated circuit technology are terms used instead of microfabrication, but microfabrication is the broad general term.
Traditional machining techniques such as electro-discharge machining, spark erosion machining, and laser drilling have been scaled from the millimeter size range to micrometer range, but they do not share the main idea of microelectronics-originated microfabrication: replication and parallel fabrication of hundreds or millions of identical structures. This parallelism is present in various imprint, casting and moulding techniques which have successfully been applied in the microregime. For example, injection moulding of DVDs involves fabrication of submicrometer-sized spots on the disc.
Processes
[edit]Microfabrication is actually a collection of technologies which are utilized in making microdevices. Some of them have very old origins, not connected to manufacturing, like lithography or etching. Polishing was borrowed from optics manufacturing, and many of the vacuum techniques come from 19th century physics research. Electroplating is also a 19th-century technique adapted to produce micrometre scale structures, as are various stamping and embossing techniques.
To fabricate a microdevice, many processes must be performed, one after the other, many times repeatedly. These processes typically include depositing a film, patterning the film with the desired micro features, and removing (or etching) portions of the film. Thin film metrology is used typically during each of these individual process steps, to ensure the film structure has the desired characteristics in terms of thickness (t), refractive index (n) and extinction coefficient (k),[2] for suitable device behavior. For example, in memory chip fabrication there are some 30 lithography steps, 10 oxidation steps, 20 etching steps, 10 doping steps, and many others are performed. The complexity of microfabrication processes can be described by their mask count. This is the number of different pattern layers that constitute the final device. Modern microprocessors are made with 30 masks while a few masks suffice for a microfluidic device or a laser diode. Microfabrication resembles multiple exposure photography, with many patterns aligned to each other to create the final structure.
Substrates
[edit]Microfabricated devices are not generally freestanding devices but are usually formed over or in a thicker support substrate. For electronic applications, semiconducting substrates such as silicon wafers can be used. For optical devices or flat panel displays, transparent substrates such as glass or quartz are common. The substrate enables easy handling of the micro device through the many fabrication steps. Often many individual devices are made together on one substrate and then singulated into separated devices toward the end of fabrication.
Deposition or growth
[edit]Microfabricated devices are typically constructed using one or more thin films (see Thin film deposition). The purpose of these thin films depends upon the type of device. Electronic devices may have thin films which are conductors (metals), insulators (dielectrics) or semiconductors. Optical devices may have films which are reflective, transparent, light guiding or scattering. Films may also have a chemical or mechanical purpose as well as for MEMS applications. Examples of deposition techniques include:
- Thermal oxidation
- Local oxidation of silicon
- Chemical vapor deposition (CVD)
- Physical vapor deposition (PVD)
- Epitaxy
Patterning
[edit]It is often desirable to pattern a film into distinct features or to form openings (or vias) in some of the layers. These features are on the micrometer or nanometer scale and the patterning technology is what defines microfabrication. This patterning technique typically uses a 'mask' to define portions of the film which will be removed. Examples of patterning techniques include:
- Photolithography
- Shadow masking
Etching
[edit]Etching is the removal of some portion of the thin film or substrate. The substrate is exposed to an etching (such as an acid or plasma) which chemically or physically attacks the film until it is removed. Etching techniques include:
- Dry etching (plasma etching) such as reactive-ion etching (RIE) or deep reactive-ion etching (DRIE)
- Wet etching or chemical etching
Microforming
[edit]Microforming is a microfabrication process of microsystem or microelectromechanical system (MEMS) "parts or structures with at least two dimensions in the submillimeter range."[3][4][5] It includes techniques such as microextrusion,[4] microstamping,[6] and microcutting.[7] These and other microforming processes have been envisioned and researched since at least 1990,[3] leading to the development of industrial- and experimental-grade manufacturing tools. However, as Fu and Chan pointed out in a 2013 state-of-the-art technology review, several issues must still be resolved before the technology can be implemented more widely, including deformation load and defects, forming system stability, mechanical properties, and other size-related effects on the crystallite (grain) structure and boundaries:[4][5][8]
In microforming, the ratio of the total surface area of grain boundaries to the material volume decreases with the decrease of specimen size and the increase of grain size. This leads to the decrease of grain boundary strengthening effect. Surface grains have lesser constraints compared to internal grains. The change of flow stress with part geometry size is partly attributed to the change of volume fraction of surface grains. In addition, the anisotropic properties of each grain become significant with the decrease of workpiece size, which results in the inhomogeneous deformation, irregular formed geometry and the variation of deformation load. There is a critical need to establish the systematic knowledge of microforming to support the design of part, process, and tooling with the consideration of size effects.[8]
Other
[edit]a wide variety of other processes for cleaning, planarizing, or modifying the chemical properties of microfabricated devices can also be performed. Some examples include:
- Doping by either thermal diffusion or ion implantation
- Chemical-mechanical planarization (CMP)
- Wafer cleaning, also known as "surface preparation" (see below)
- Wire bonding
Cleanliness in wafer fabrication
[edit]Microfabrication is carried out in cleanrooms, where air has been filtered of particle contamination and temperature, humidity, vibrations and electrical disturbances are under stringent control. Smoke, dust, bacteria and cells are micrometers in size, and their presence will destroy the functionality of a microfabricated device.
Cleanrooms provide passive cleanliness but the wafers are also actively cleaned before every critical step. RCA-1 clean in ammonia-peroxide solution removes organic contamination and particles; RCA-2 cleaning in hydrogen chloride-peroxide mixture removes metallic impurities. Sulfuric acid-peroxide mixture (a.k.a. Piranha) removes organics. Hydrogen fluoride removes native oxide from silicon surface. These are all wet cleaning steps in solutions. Dry cleaning methods include oxygen and argon plasma treatments to remove unwanted surface layers, or hydrogen bake at elevated temperature to remove native oxide before epitaxy. Pre-gate cleaning is the most critical cleaning step in CMOS fabrication: it ensures that the ca. 2 nm thick oxide of a MOS transistor can be grown in an orderly fashion. Oxidation, and all high temperature steps are very sensitive to contamination, and cleaning steps must precede high temperature steps.
Surface preparation is just a different viewpoint, all the steps are the same as described above: it is about leaving the wafer surface in a controlled and well known state before you start processing. Wafers are contaminated by previous process steps (e.g. metals bombarded from chamber walls by energetic ions during ion implantation), or they may have gathered polymers from wafer boxes, and this might be different depending on wait time.
Wafer cleaning and surface preparation work similarly to the machines in a bowling alley: first they remove all unwanted bits and pieces, and then they reconstruct the desired pattern so that the game can go on.
See also
[edit]References
[edit]- ^ Nitaigour Premchand Mahalik (2006) "Micromanufacturing and Nanotechnology", Springer, ISBN 3-540-25377-7
- ^ Löper, Philipp; Stuckelberger, Michael; Niesen, Bjoern; Werner, Jérémie; Filipič, Miha; Moon, Soo-Jin; Yum, Jun-Ho; Topič, Marko; De Wolf, Stefaan; Ballif, Christophe (2015). "Complex Refractive Index Spectra of CH3NH3PbI3 Perovskite Thin Films Determined by Spectroscopic Ellipsometry and Spectrophotometry". The Journal of Physical Chemistry Letters. 6 (1): 66–71. doi:10.1021/jz502471h. PMID 26263093. Retrieved 2021-11-16.
- ^ a b Engel, U.; Eckstein, R. (2002). "Microforming - From Basic research to its realization". Journal of Materials Processing Technology. 125–126 (2002): 35–44. doi:10.1016/S0924-0136(02)00415-6.
- ^ a b c Dixit, U.S.; Das, R. (2012). "Chapter 15: Microextrusion". In Jain, V.K. (ed.). Micromanufacturing Processes. CRC Press. pp. 263–282. ISBN 9781439852903.
- ^ a b Razali, A.R.; Qin, Y. (2013). "A review on micro-manufacturing, micro-forming and their key issues". Procedia Engineering. 53 (2013): 665–672. doi:10.1016/j.proeng.2013.02.086.
- ^ Advanced Manufacturing Processes Laboratory (2015). "Process Analysis and Variation Control in Micro-stamping". Northwestern University. Retrieved 18 March 2016.
- ^ Fu, M.W.; Chan, W.L. (2014). "Chapter 4: Microforming Processes". Micro-scaled Products Development via Microforming: Deformation Behaviours, Processes, Tooling and its Realization. Springer Science & Business Media. pp. 73–130. ISBN 9781447163268.
- ^ a b Fu, M.W.; Chan, W.L. (2013). "A review on the state-of-the-art microforming technologies". International Journal of Advanced Manufacturing Technology. 67 (9): 2411–2437. doi:10.1007/s00170-012-4661-7. S2CID 110879846.
Further reading
[edit]Journals
- Journal of Microelectromechanical Systems (J.MEMS)
- Sensors and Actuators A: Physical
- Sensors and Actuators B: Chemical
- Journal of Micromechanics and Microengineering
- Lab on a Chip
- IEEE Transactions of Electron Devices
- Journal of Vacuum Science and Technology A: Vacuum, Surfaces, Films
- Journal of Vacuum Science and Technology B: Microelectronics and Nanometer Structures: Processing, Measurement, and Phenomena
Books
- Franssila, S. (2010). Introduction to Microfabrication (2nd ed.). Wiley. doi:10.1002/9781119990413. ISBN 978-1-119-99041-3.
- Madou, M.J. (2002). Fundamentals of Microfabrication (2nd ed.). CRC Press. doi:10.1201/9781482274004. ISBN 0-8493-0826-7.
- Kovacs, G.T.A. (1998). Micromachined Transducers Sourcebook. McGraw-Hill. ISBN 0-07-290722-3.
- Brodie, I.; Muray, J.J. (1982). The Physics of Microfabrication. Plenum Press. doi:10.1007/978-1-4899-2160-4. ISBN 1-4899-2160-5.
- Mahalik, N.P. (2006). Micromanufacturing and Nanotechnology. Springer. doi:10.1007/3-540-29339-6. ISBN 3-540-25377-7.
- Widmann, D.; Mader, H.; Friedrich, H. (2000). Technology of Integrated Circuits. Springer. doi:10.1007/978-3-662-04160-4. ISBN 978-3-662-04160-4.
- Plummer, J.D.; Deal, M.D.; Griffin, P.B. (2012). Silicon VLSI Technology (2nd ed.). Prentice Hall. ISBN 978-0-13-614156-3. OCLC 753300108.
- May, G.S.; Sze, S.S. (2004). Fundamentals of Semiconductor Processing. Wiley. ISBN 978-0-471-23279-7. OCLC 52333554.
- van Zant, P. (2014). Microchip Fabrication (6th ed.). McGraw-Hill. p. 1302905242. ISBN 978-0-07-182101-8.
- Jaeger, R.C. (2002). Introduction to Microelectronic Fabrication (2nd ed.). Prentice Hall. ISBN 0-201-44494-1. OCLC 48226051.
- Wolf, S.; Tauber, R.N. (2000). Process technology. Silicon Processing for the VLSI Era. Vol. 1. Lattice Press. ISBN 0-9616721-6-1.
- Campbell, S.A. (2001). The Science and Engineering of Microelectronic Fabrication (2nd ed.). Oxford University Press. ISBN 0-19-513605-5. OCLC 45209102.
- Hattori, T. (2011). Ultraclean Surface Processing of Silicon Wafers: Secrets of VLSI Manufacturing. Springer. ISBN 978-3-642-08272-6. OCLC 751530070.
- Geschke, O.; Klank, H.; Telleman, P., eds. (2004). Microsystem Engineering of Lab-on-a-chip Devices. Wiley. doi:10.1002/3527601651. ISBN 3-527-30733-8.
- Meyrueis, P.; Sakoda, K.; Van de Voorde, M., eds. (2017). Micro- and Nanophotonic Technologies. Wiley. doi:10.1002/9783527800728. ISBN 978-3-527-34037-8.
External links
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