三氟乙酸铋(III)是一种无机化合物,化学式为Bi(O2CCF3)3。它可由三氟乙酸银和碘化铋在120 °C反应得到:[2]
- 3 CF3COOAg + BiI3 → (CF3COO)3Bi + 3 AgI
它也可由三氟乙酸银和氯化铋在二氯甲烷中反应得到。[1]它和四芳基硼酸钠反应,可以得到三芳基铋。[3]
- ^ 1.0 1.1 C. David Garner, Barry Hughes. Inorganic compounds containing the trifluoroacetate group. IV. Preparation and properties of arsenic tris(trifluoroacetate), [As(O2CCF3)], and related compounds. Inorganic Chemistry. 1975-07, 14 (7): 1722–1724 [2021-08-09]. ISSN 0020-1669. doi:10.1021/ic50149a061. (原始内容存档于2021-08-09) (英语).
- ^ 2.0 2.1 Tn Bell, Bj Pullman, Bo West. Perfluoroalkylbismuth Compounds. I. Mixed Alkylperfluoroalkyl Derivatives. Australian Journal of Chemistry. 1963, 16 (4): 636 [2021-08-09]. ISSN 0004-9425. doi:10.1071/CH9630636 (英语).
- ^ Vitalie Stavila, John H. Thurston, Darío Prieto-Centurión, Kenton H. Whitmire. A New Methodology for Synthesis of Aryl Bismuth Compounds: Arylation of Bismuth(III) Carboxylates by Sodium Tetraarylborate Salts. Organometallics. 2007-12-01, 26 (27): 6864–6866 [2021-08-09]. ISSN 0276-7333. doi:10.1021/om7009667 (英语).