亚苄基丙酮三羰基铁是一种有机铁化合物,化学式为(C6H5CH=CHC(O)CH3)Fe(CO)3,可简写为(bda)Fe(CO)3,这种红色固体是Fe(CO)3单元的转移试剂。[1]
它可由Fe2(CO)9和亚苄基丙酮反应制得。[2]它可以和路易斯碱形成加合物,反应过程中bda配体不会被取代。[3]
- ^ Knölker, H.-J. "(η4-Benzylideneacetone)tricarbonyliron" in Encyclopedia of Reagents for Organic Synthesis (Ed: L. Paquette) 2004, J. Wiley & Sons, New York. doi:10.1002/047084289X.
- ^ Domingos, A. J. P.; Howell, J. A. S.; Johnson, B. F. G.; Lewis, J. Reagents for the Synthesis of η-Diene Complexes of Tricarbonnyliron and Tricarbonylruthenium. Inorg. Synth. 1990, 28: 52–55. doi:10.1002/9780470132593.ch11.
- ^ Howell, J. A. S.; Kola, J. C.; Dixon, D. T.; Burkinshaw, P. M.; Thomas, M. J. The kinetics and mechanism of diene exchange in (η4-enone)Fe(CO)2L complexes (L = phosphine, phosphite). Journal of Organometallic Chemistry. 1984, 266: 83–96. doi:10.1016/0022-328X(84)80113-8.
- Alcock, N. W.; Richards, C. J.; Thomas, S. E. Preparation of Tricarbonyl(η4-vinylketene)iron(0) Complexes from Tricarbonyl(ε4-vinyl ketone)iron(0) Complexes and Their Subsequent Conversion to Tricarbonyl(ε4-vinylketenimine)iron(0) Complexes. Organometallics. 1991, 10: 231–238. doi:10.1021/om00047a054.
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| 铁(-II) | |
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| 铁(0) | |
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| 铁(I) | |
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| 铁(0,II) | |
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| 铁(II) | |
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| 铁(0,III) | |
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| 铁(II,III) | |
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| 铁(III) | |
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| 铁(VI) | |
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