1,4-戊二烯 - 维基百科,自由的百科全书
1,4-戊二烯 | |
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识别 | |
CAS号 | 591-93-5 ![]() |
性质 | |
化学式 | C5H8 |
摩尔质量 | 68.12 g·mol−1 |
外观 | 无色液体 |
密度 | 0.657 g·cm−3(26 °C)[1] |
熔点 | −148.8 °C(124.3 K)[2] |
沸点 | 26 °C(299 K)[2] |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
1,4-戊二烯是一种有机化合物,化学式为C5H8。它可由1,5-戊二醇二乙酸酯的分解或α-烯丙基-β-溴乙基乙醚和锌及氯化锌在正丁醇中反应制得。[3]它加氢可以得到戊烷。[4]它在金属有机化合物中可作为配体。[5]
参考文献
[编辑]- ^ L. E. Schniepp, H. H. Geller. The Preparation of 1,3- and 1,4-Pentadienes from Furfural. Journal of the American Chemical Society. 1945-01, 67 (1): 54–56 [2022-01-04]. ISSN 0002-7863. doi:10.1021/ja01217a018. (原始内容存档于2022-01-04) (英语).
- ^ 2.0 2.1 "PhysProp" data were obtained from Syracuse Research Corporation of Syracuse, New York (US). Retrieved from SciFinder. [2022-01-04].
- ^ 1,4-PENTADIENE. Organic Syntheses. 1958, 38: 78 [2022-01-04]. doi:10.15227/orgsyn.038.0078. (原始内容存档于2022-03-01).
- ^ Mario Castiglioni, Roberto Giordano, Enrico Sappa. (η5-C5H5)NiRu3(μ-H)3(CO)9, Ru3(CO)12 and (η5-C5H5)2Ni2(CO)2 as heterogeneous catalyst precursors: hydrogenation, dehydrogenation and isomerization of linear and cyclic monoenes and dienes, and of aromatic hydrocarbons. Journal of Molecular Catalysis. 1987-11, 42 (3): 307–322 [2022-01-04]. doi:10.1016/0304-5102(87)85005-8. (原始内容存档于2018-06-28) (英语).
- ^ Marko Hapke, Nico Weding, Anke Spannenberg. Highly Reactive Cyclopentadienylcobalt(I) Olefin Complexes. Organometallics. 2010-10-11, 29 (19): 4298–4304 [2022-01-04]. ISSN 0276-7333. doi:10.1021/om100692k. (原始内容存档于2022-01-04) (英语).